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B Stabilized phosphorescence spectra of monomer MDP and MND in two-methyltetrahydrofuran (1 × 10−5 M) at the 77 K (top), and polymer PDA and PNA on the place-temperature (RT) (bottom) delighted in the 280 and you may 360 nm. C Polymer film excitation–phosphorescence mapping of PDA (top) and PNA (bottom) at the space-temperature. Elizabeth Natural transition orbitals on the straight down triplet change of MDP and you may MND regarding the gaseous state. It’s very worth of detailing the homochiral Roentgen-BINAP and you can S-BINAP exhibited refined differences in the fresh spectral molds of 1’s circularly polarized luminescence (CPL) signals found inside Second Fig. Also, but they brought various other phosphorescent targets the brand new polymer strings to help you prepare yourself RTP tool with tunable phosphorescence emission of blue to help you purple-coloured .
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